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You have, undoubtedly, heard of Herschel's discovery concerning the production of heat by invisible rays emitted from the sun. By placing one thermometer within the red rays, separated by a prism, and another beyond them, he found the temperature of the outside thermometer raised more than that of the inside one.

When I first heard of Mr. Tennant's discovery,* I was very much struck by an observation which you long ago made to me, on the fertility of the Cornish lands, in which there was decomposed, feltspar or serpentine.

Mr. Tennant spent a day here some time ago, when I mentioned your observation to him, but he could not give any solution of the phenomenon. Quere. As lime and magnesia are probably both subservient to vegetation, only from supplying plants with carbonic acid, may not lime, when mingled with magnesia, in the process of vegetation, render it partially caustic, and thus enable it to destroy them?

Your observation on the scale of numbers, and the fact relative to it, are highly interesting. Reasoning on this subject would literally form the logic of generalization, or the application of one term to signify many terms, or many ideas, on which science ultimately depends. Quere.-How far have the first attempts at generalization arisen from accident, and how far from the resemblance between ideas?

Dr. Beddoes has always ridiculed the "Tractors," in common with all other reasonable men. He is about to publish a new work on the Nitrous Acid.

J. Wedgwood is returned, very little altered for the better. Coleridge is gone to reside in Cumberland; he was here the week before last, and spent much time with me, and often spoke of you with the greatest interest. Clayfield is at this moment chiefly engaged in commercial speculations. He has found a new mode of making soda, which there is every reason to believe will turn out profitable.

I hope some time in the autumn to see you, and to enjoy the well remembered pleasure of your conversation; in the mean while, I remain, with respects to your family,

Yours with sincere affection,

HUMPHRY DAVY.

Davy here alludes to the fact of magnesian earth being prejudicial to vegetation.

In estimating the early genius of Davy, and his character as a philosopher, the style and matter of his RESEARCHES" will afford us much assistance. The close philosophical reasoning,-the patient and penetrating industry,the candid submission to every intimation of experiment, and the accuracy of manipulation, so remarkably displayed throughout this work, have been rarely equalled, and perhaps never surpassed.

There is scarcely to be found a more striking illustration of chemical genius, than that afforded by his chapter on the "Absorption of Nitrous Gas, by solutions of green Sulphate of Iron."

The address with which he gradually disentangles the subject of its difficulties, and catches at every opening to truth, affords a study which may be safely recommended to the attention of every young experimentalist, as being no less instructive than it is beautiful.

The phenomena attending the absorption of nitrous gas by solutions of sulphate of iron had been examined by Vauquelin and by Berthollet, but the conclusions of these chemical philosophers were fatally infected by errors, arising from the neglected action of the atmosphere. Davy, by conducting his experiments over mercury, proved that, in the absence of air, the absorption was simply owing to a combination between the gas and the fluid, but that, on admitting air, the nitrous gas became nitrous acid, a portion of which, together with a part of the water, subsequently underwent decomposition, and gave origin to ammonia, and ultimately to nitrate of ammonia, while the iron passed into the state of a peroxide.

We have also to admire in this work an ardour for investigation, which even the most imminent personal danger could not repress. He may truly be said to have sought the bubble reputation in the very jaws of Death. What shall we say of that spirit which led him to inspire nitrous gas, at the hazard of filling his lungs with the vapour of aqua fortis! or what, of that intrepid coolness which enabled him to breathe a deadly gas, and to watch the advances of its chilling power in the ebbing pulsations at the wrist!

These experiments, however, are far too interesting and important to be related in any other than the author's own words; but it is first necessary that his trials with the nitrous oxide should be considered.

He found that this gas might be most conveniently, as well as most economically, prepared by the decomposition of a salt known by the name of nitrate of ammonia, by the application of a regulated heat; but, as the researches by which he arrived at this conclusion are recorded at length in his

work, and as the most important of them are now embodied in every elementary system of chemistry, it would not only be tedious but useless, to enter into a detail of them upon this occasion.

"In April," he says, "I obtained nitrous oxide in a state of purity, and ascertained many of its chemical properties. Reflections upon these properties, and upon former trials, made me resolve to inspire it in its pure form, for I saw no other way in which its respirability, or powers, could be determined.

"I was aware of the danger of the experiment. It certainly would never have been made, if the hypothesis of Dr. Mitchell had in the least influenced my mind. I thought that the effects might, possibly, be depressing and painful, but there were many reasons which induced me to believe, that a single inspiration of a gas, apparently possessing no immediate action on the irritable fibre, could neither destroy, nor materially injure the powers of life.

"On April 11th, I made the first inspiration of pure nitrous oxide. It passed through the bronchie without stimulating the glottis, and produced no uneasy sensations in the lungs.

The result of this experiment proved that the gas was respirable, and induced me to believe that a farther trial of its effects might be made without danger.

"On April 16th, Dr. Kinglake being accidentally present, I breathed three quarts of nitrous oxide from and into a silk bag, for more than half a minute, without previously closing my nose, or exhausting my lungs. The first inspirations occasioned a slight degree of giddiness, which was succeeded by an uncommon sense of fulness in the head, accompanied with loss of distinct sensation and voluntary power,—a feeling analogous to that produced in the first stage of intoxication; but unattended by pleasurable sensation. Dr. Kinglake, who felt my pulse, informed me that it was rendered quicker and fuller.

"This trial did not satisfy me with regard to its powers; comparing it with the former ones, I was unable to determine whether the operation was stimulant or depressing.

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"I communicated the result to Dr. Beddoes, and on April the 17th, he was present when the following experiment was made.

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Having previously closed my nostrils, and exhausted my lungs, I breathed four quarts of the gas, from and into a silk bag. The first feelings were similar to those produced in the last experiment; but in less than half

a minute, the respiration being continued, they diminished gradually, and were succeeded by a sensation analogous to gentle pressure on all the muscles, attended by an highly pleasurable thrilling, particularly in the chest and in the extremities. The objects around me became dazzling, and my hearing more acute. Towards the last inspirations, the thrilling increased, the sense of muscular power became greater, and, at last, an irresistible propensity to action was indulged in; I recollect but indistinctly what followed; I know that my motions were various and violent.

"These effects very soon ceased after the respiration of the gas. In ten minutes I had recovered my natural state of mind. The thrilling in the extremities continued longer than the other sensations.

"This experiment was made in the morning; no languor or exhaustion was consequent; my feelings throughout the day were as usual, and I passed the night in undisturbed repose.

"The next morning the recollection of the effects of the gas was very indistinct; and had not remarks written immediately after the experiment recalled them to my mind, I should even have questioned their reality.”

Our philosopher very naturally doubted whether some of these strong emotions might not, after all, be attributed to the enthusiasm necessarily connected with the perception of agreeable feelings, when he was prepared to expect painful sensations; but he says, that subsequent experiments convinced him that the effects were solely owing to the specific operation of the gas. He found that he could breathe nine quarts of nitrous oxide for three minutes, and twelve quarts for rather more than four; but that he could never breathe it, in any quantity, so long as five minutes. Whenever its operation was carried to the highest extent, the pleasurable thrilling, at its height about the middle of the experiment, gradually diminished, the sense of pressure on the muscles was lost, impressions ceased to be perceived, vivid ideas passed rapidly through the mind, and voluntary power was altogether destroyed, so that the mouth-piece generally dropped from his unclosed lips. When he breathed from six to seven quarts, muscular motions were produced to a great extent; sometimes he manifested his pleasure by stamping, or laughing only; at other times, by dancing round the room, and vociferating.

During the progress of these experiments, it occurred to him that, supposing nitrous oxide to be analogous in its operation to common stimulants, the debility occasioned by intoxication from fermented liquors ought to be

increased after excitement from this gas, in the same manner as the debility produced by two bottles of wine is increased by a third. To ascertain whether this was the case, he drank a bottle of wine, in large draughts, in less than eight minutes. His usual drink, he tells us, was water; he had been little accustomed to take spirits, or wine, and had never been intoxicated, but once before, in the course of his life. Under such circumstances, we may readily account for the powerful effects produced by this quantity of wine, and which he describes in the following manner :

"Whilst I was drinking, I perceived a sense of fulness in the head, and throbbing of the arteries, not unlike that produced in the first stage of nitrous oxide excitement: after I had finished the bottle, this fulness increased, the objects around me became dazzling, the power of distinct articulation was lost, and I was unable to stand steadily. At this moment, the sensations were rather pleasurable than otherwise; the sense of fulness in the head, however, soon increased, so as to become painful, and in less than an hour I sunk into a state of insensibility. In this situation I must have remained for two hours, or two hours and a half. I was awakened by head-ache and painful nausea. My bodily and mental debility were excessive, and the pulse feeble and quick.

"In this state, I breathed for near a minute and a half five quarts of gas, which was brought to me by the operator for nitrous oxide; but as it produced no sensations whatever, and apparently rather increased my debility, I am almost convinced that it was, from some accident, either common air, or very impure nitrous oxide.

"Immediately after this trial, I respired twelve quarts of oxygen for nearly four minutes. It produced no alteration in my sensations at the time, but immediately afterwards I imagined that I was a little exhilarated.

"The head-ache and debility still, however, continuing with violence, I examined some nitrous oxide which had been prepared in the morning, and finding it very pure, I respired seven quarts of it for two minutes and a half. I was unconscious of head-ache after the third inspiration; the usual pleasurable thrilling was produced, voluntary power was destroyed, and vivid ideas rapidly passed through my mind; I made strides across the room, and continued for some minutes much exhilarated; but languor and depression, not very different in degree from those existing before the experiment, succeeded; they however gradually went off before bed-time,

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