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"I am sorry to say, I think the system carried too far in England. God forbid, that any useful light should be extinguished! let the persons who wish for education receive it; but it appears to me that, in the great cities in Eng land, it is, as it were, forced upon the population; and that sciences, which the lower classes can only very superficially acquire, are presented to them; in consequence of which they often become idle and conceited, and above their usual laborious occupations. The unripe fruit of the tree of knowledge is, I believe, always bitter or sour; and scepticism and discontentment—sicknesses of the mind-are often the result of devouring it."

Methinks I hear the reader exclaim-" How little could Davy imagine that his prophetic words would have been so soon fulfilled !"-But I would seriously recommend to the President of the Mechanics' Institute, an anecdote which, if properly applied, cannot fail to be instructive. When Diogenes, trampling with his dirty feet on the embroidered couch of Plato, cried out“Thus do I trample on the pride of Plato!" the philosopher shook his head, and replied—“ Truly, but with more pride thou dost it, good Diogenes."

CHAPTER XV.

Sir H. Davy's Paper on the Phenomena of Volcanoes. His experiments on Vesuvius.Theory of Volcanic action.-His reception abroad.-Anecdotes. His last Letter to Mr. Poole from Rome. -His Paper on the electricity of the Torpedo.-Consolations in Travel, or the Last Days of a Philosopher.-Analysis of the work.-Reflections suggested by its style and composition.-Davy and Wollaston compared. His last illness.-Arrival at Geneva. HIS DEATH.

A SHORT time before Sir Humphry Davy quitted England, to which he was destined never to return, he communicated to the Royal Society a paper 'On the Phenomena of Volcanoes;" which was read on the 20th of March 1828, and published in the Transactions of that year.

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The object of this memoir was to collect and record the various observations and experiments which he had made on Vesuvius, during his several visits to that volcano. The appearances which it presented in 1814 and 1815 have been already noticed; it was in December 1819, and during the two succeeding months, that the mountain offered a favourable opportunity for making those experiments which form the principal subject of the present communication.

It was a point of great importance to determine whether any combustion was going on at the moment the lava issued from the mountain; for this fact being once discovered, and the nature of the combustible matter ascertained, we should gain an immense step towards a just theory of the sources of volcanic action. For this purpose, he carefully examined both the lava and the elastic fluids with which it was accompanied. He was unable, however, to detect any thing like deflagration with nitre, which must have taken place had the smallest quantity of carbonaceous matter been present; nor could he, by exposing the ignited mass to portions of atmospheric air, discover that any appreciable quantity of oxygen had been absorbed. On immersing fused lava in water, no decomposition of that fluid followed, so that there could not have

existed any quantity of the metallic bases of the alkalies or earths. Common salt, chloride of iron, the sulphates and muriates of potash, and soda, generally constituted the mass of solid products; while steam, muriatic acid fumes, and occasionally sulphurous acid vapours, formed the principal elastic matters disengaged.

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He informs us it was on the 26th of January 1820, that he had the honour to accompany his Royal Highness the Prince of Denmark in an excursion to the mountain, on which occasion his friend, Cavalier Monticelli, was also sent. At this time, the lava was seen nearly white hot through a chasm near the place where it flowed from the mountain; and yet, although he threw nitre upon it in large quantities through this chasm, there was no more increase of ignition than when the experiment was made on lava exposed to the free air. He observed that the appearance of the sublimations was very different from that which they had presented on former occasions; those near the aperture were coloured green and blue by salt of copper; but there was, as usual, a great quantity of muriate of iron. On the 5th, the sublimate of the lava was pure chloride of sodium; in the sublimate of January 6th, there were both sulphate of soda and indications of sulphate of potash; but in those which he collected during this last visit, the sulphate of soda was in much larger quantities, and there was much more of a salt of potash.

For nearly three months the craters, of which there were two, were in activity. The larger one threw up showers of ignited ashes and stones to a height apparently of from two hundred to two hundred and fifty feet; and from the smaller crater steam arose with great violence. Whenever the crater could be approached, it was found incrusted with saline matter: and the walk to the edge of the small crater, on the 6th of January, was through a mass of loose saline matter, principally common salt coloured by muriate of iron, in which the foot sunk to some depth. It was easy, even at a great distance, to distinguish between the steam disengaged by one of the craters, and the earthy matter thrown up by the other. The steam appeared white in the day, and formed perfectly white clouds, which reflected the morning and evening light of the purest tints of red and orange. The earthy matter always appeared as a black smoke, forming dark clouds, and in the night it was highly luminous at the moment of the explosion.

He concludes this paper on Volcanoes with some observations on the theory of their phenomena. "It appears," says he, "almost demonstrable, that none of the chemical causes anciently assigned for volcanic fires can be

true. Amongst these, the combustion of mineral coal is one of the most current; but it seems wholly inadequate to account for the phenomena. However large the stratum of pit-coal, its combustion under the surface could never produce violent and excessive heat; for the production of carbonic acid gas, when there was no free circulation of air, must tend constantly to impede the process and it is scarcely possible that carbonaceous matter, if such a cause existed, should not be found in the lava, and be disengaged with the saline or aqueous products from the bocca or craters. There are many instances in England of strata of mineral coal which have been long burning; but the results have been merely baked clay and schists, and it has produced no result similar to lava.

"If the idea of Lemery were correct, that the action of sulphur on iron may be a cause of volcanic fires, sulphate of iron ought to be the great product of the volcano; which is known not to be the case; and the heat produced by the action of sulphur on the common metals is quite inadequate to account for the appearances. When it is considered that volcanic fires occur and intermit with all the phenomena that indicate intense chemical action, it seems not unreasonable to refer them to chemical causes. But for phenomena upon such a scale, an immense mass of matter must be in activity, and the products of the volcano ought to give an idea of the nature of the substances primarily active. Now, what are these products? Mixtures of the earths in an oxidated and fused state, and intensely ignited; water and saline substances, such as might be furnished by the sea and air, altered in such a manner as might be expected from the formation of fixed oxidated matter. But it may be said, if the oxidation of the metals of the earths be the causes of the phenomena, some of these substances ought occasionally to be found in the lava, or the combustion ought to be increased at the moment the materials passed into the atmosphere. But the reply to this objection is, that it is evident that the changes which occasion volcanic fires take place in immense subterranean cavities; and that the access of air to the acting substances occurs long before they reach the exterior surface.

"There is no question but that the ground under the solfaterra is hollow; and there is scarcely any reason to doubt of a subterraneous communication between this crater and that of Vesuvius: whenever Vesuvius is in an active state, the solfaterra is comparatively tranquil. I examined the bocca of the solfaterra on the 21st of February 1820, two days before the activity of Vesuvius was at its height: the columns of steam which usually arise in large

quantities when Vesuvius is tranquil, were now scarcely visible, and a piece of paper thrown into the aperture did not rise again; so that there was every reason to suppose the existence of a descending current of air. The subterraneous thunder heard at such great distances under Vesuvius is almost a demonstration of the existence of great cavities below filled with aëriform matter: and the same excavations which, in the active state of the volcano, throw out, during so great a length of time, immense volumes of steam, must, there is every reason to believe, in its quiet state, become filled with atmospheric air.*

"To what extent subterraneous cavities may exist, even in common rocks, is shown in the limestone caverns of Carniola, some of which contain many hundred thousand cubical feet of air; and in proportion as the depth of an excavation is greater, so is the air more fit for combustion.

"The same circumstances which would give alloys of the metals of the earths the power of producing volcanic phenomena, namely, their extreme facility of oxidation, must likewise prevent them from ever being found in a pure combustible state in the products of volcanic eruptions; for before they reach the external surface, they must not only be exposed to the air in the subterranean cavities, but be propelled by steam; which must possess, under the circumstances, at least the same facility of oxidating them as air. Assuming the hypothesis of the existence of such alloys of the metals of the earths as may burn into lava in the interior, the whole phenomena may be easily explained from the action of the water of the sea and air on those metals; nor is there any fact, or any of the circumstances which I have mentioned in the preceding part of this paper, which cannot be easily explained according to that hypothesis. For almost all the volcanoes in the old world of considerable magnitude are near, or at no considerable distance from the sea: and if it be assumed that the first eruptions are produced by the action of sea water upon the metals of the earths, and that considerable cavities are left by the oxidated metals thrown out as lava, the results of their action are such as might be anticipated; for, after the first eruptions, the oxidations which produce the subsequent ones may take place in the caverns below the surface; and when the sea is distant, as in the volcanoes of South America,

* "Vesuvius is a mountain admirably fitted, from its form and situation, for experiments on the effect of its attraction on the pendulum: and it would be easy in this way to determine the problem of its cavities. On Etna the problem might be solved on a larger scale."

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